Characterization, crystallization and two three dimensional structures of the N10- formyltetrahydrofolate synthetase (FTHFS) from the syntrophic acetate oxidizing bacterium Tepidanaerobacter acetatoxydans Re1

The crystal structure of N10- formyltetrahydrofolate synthetase 1 (FTHFS 1) and N10- formyltetrahydrofolate synthetase 2 (FTHFS 2) from the syntrophic acetate oxidizing bacterium, Tepidanaerobacter acetatoxydans Re1, was solved by x-ray crystallography to a resolution of 2.15 Å, and 2.30 Å resolutio...

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Detalles Bibliográficos
Autor principal: Bergdahl, Roland
Formato: Second cycle, A2E
Lenguaje:sueco
Inglés
Publicado: 2012
Materias:
Acceso en línea:https://stud.epsilon.slu.se/5058/
Descripción
Sumario:The crystal structure of N10- formyltetrahydrofolate synthetase 1 (FTHFS 1) and N10- formyltetrahydrofolate synthetase 2 (FTHFS 2) from the syntrophic acetate oxidizing bacterium, Tepidanaerobacter acetatoxydans Re1, was solved by x-ray crystallography to a resolution of 2.15 Å, and 2.30 Å resolution, respectively. The FTHFS 1 crystal structure has four non-crystallographic related protein molecules in the asymmetric unit of the crystal, while FTHFS 2 has two. The pH optimum in the formylation reaction for FTHFS 1 was determined to be 7.5, while FTHFS 2 had a pH optimum of 9, and it was determined that both enzymes had a temperature optimum of 60°C for their formulation reactions. An attempt to perform the deformylation reaction with both enzymes was unsuccessfully carried out.