Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics

Here, we characterize two novel GH5 endoglucanases (GH5CelA and GH5CelB) from an uncultured bacterium identified in termite gut microbiomes. Both genes were codon-optimized, synthetized, cloned, and expressed as recombinant proteins in Escherichia coli for subsequent purification. Both enzymes showe...

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Autores principales: Ben Guerrero, Emiliano, Marrero Diaz De Villegas, Ruben, Soria, Marcelo Abel, Santangelo, María De La Paz, Campos, Eleonora, Talia, Paola Mónica
Formato: info:ar-repo/semantics/artículo
Lenguaje:Inglés
Publicado: Springer 2020
Materias:
Acceso en línea:http://hdl.handle.net/20.500.12123/7767
https://link.springer.com/article/10.1007/s00253-020-10831-5
https://doi.org/10.1007/s00253-020-10831-5
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author Ben Guerrero, Emiliano
Marrero Diaz De Villegas, Ruben
Soria, Marcelo Abel
Santangelo, María De La Paz
Campos, Eleonora
Talia, Paola Mónica
author_browse Ben Guerrero, Emiliano
Campos, Eleonora
Marrero Diaz De Villegas, Ruben
Santangelo, María De La Paz
Soria, Marcelo Abel
Talia, Paola Mónica
author_facet Ben Guerrero, Emiliano
Marrero Diaz De Villegas, Ruben
Soria, Marcelo Abel
Santangelo, María De La Paz
Campos, Eleonora
Talia, Paola Mónica
author_sort Ben Guerrero, Emiliano
collection INTA Digital
description Here, we characterize two novel GH5 endoglucanases (GH5CelA and GH5CelB) from an uncultured bacterium identified in termite gut microbiomes. Both genes were codon-optimized, synthetized, cloned, and expressed as recombinant proteins in Escherichia coli for subsequent purification. Both enzymes showed activity on the pNPC and barley β-glucan substrates, whereas GH5CelB also showed low activity on carboxymethyl cellulose. The optimum conditions for both enzymes were an acid pH (5) and moderate temperature (35 to 50 °C). The enzymes differed in the kinetic profiles and patterns of the generated hydrolysis products. A structural-based modeling analysis indicated that both enzymes possess a typical (β/α)8-barrel fold characteristic of GH5 family, with some differential features in the active site cleft. Also, GH5CelB presents a putative secondary binding site. Furthermore, adjacent to the active site of GH5CelA and GH5CelB, a whole subdomain rarely found in GH5 family may participate in substrate binding and thermal stability. Therefore, GH5CelA may be a good candidate for the production of cello-oligosaccharides of different degrees of polymerization applicable for feed and food industries, including prebiotics. On the other hand, GH5CelB could be useful in an enzymatic cocktail for the production of lignocellulosic bioethanol, because of the production of glucose as a hydrolysis product.
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spelling INTA77672020-08-25T13:02:31Z Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics Ben Guerrero, Emiliano Marrero Diaz De Villegas, Ruben Soria, Marcelo Abel Santangelo, María De La Paz Campos, Eleonora Talia, Paola Mónica Genomas Glucanos Isoptera Identificación Genomes Glucans Identification Endoglucanases Termites Here, we characterize two novel GH5 endoglucanases (GH5CelA and GH5CelB) from an uncultured bacterium identified in termite gut microbiomes. Both genes were codon-optimized, synthetized, cloned, and expressed as recombinant proteins in Escherichia coli for subsequent purification. Both enzymes showed activity on the pNPC and barley β-glucan substrates, whereas GH5CelB also showed low activity on carboxymethyl cellulose. The optimum conditions for both enzymes were an acid pH (5) and moderate temperature (35 to 50 °C). The enzymes differed in the kinetic profiles and patterns of the generated hydrolysis products. A structural-based modeling analysis indicated that both enzymes possess a typical (β/α)8-barrel fold characteristic of GH5 family, with some differential features in the active site cleft. Also, GH5CelB presents a putative secondary binding site. Furthermore, adjacent to the active site of GH5CelA and GH5CelB, a whole subdomain rarely found in GH5 family may participate in substrate binding and thermal stability. Therefore, GH5CelA may be a good candidate for the production of cello-oligosaccharides of different degrees of polymerization applicable for feed and food industries, including prebiotics. On the other hand, GH5CelB could be useful in an enzymatic cocktail for the production of lignocellulosic bioethanol, because of the production of glucose as a hydrolysis product. Instituto de Biotecnología Fil: Ben Guerrero, Emiliano. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Biotecnología. Instituto de Agrobiotecnología y Biología Molecular. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Agrobiotecnología y Biología Molecular; Argentina Fil: Marrero Diaz De Villegas, Ruben. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Biotecnología. Instituto de Agrobiotecnología y Biología Molecular. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Agrobiotecnología y Biología Molecular; Argentin Fil: Soria, Marcelo Abel. Universidad de Buenos Aires. Facultad de Agronomía. Cátedra de Microbiología Agrícola; Argentina Fil: Santangelo, María De La Paz. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Biotecnología. Instituto de Agrobiotecnología y Biología Molecular. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Agrobiotecnología y Biología Molecular; Argentina Fil: Campos, Eleonora. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Biotecnología. Instituto de Agrobiotecnología y Biología Molecular. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Agrobiotecnología y Biología Molecular; Argentina Fil: Talia, Paola Mónica. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Biotecnología. Instituto de Agrobiotecnología y Biología Molecular. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Agrobiotecnología y Biología Molecular; Argentina 2020-08-25T12:56:46Z 2020-08-25T12:56:46Z 2020-08 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://hdl.handle.net/20.500.12123/7767 https://link.springer.com/article/10.1007/s00253-020-10831-5 0175-7598 1432-0614 https://doi.org/10.1007/s00253-020-10831-5 eng info:eu-repograntAgreement/INTA/PNAIyAV/1130034/AR./Desarrollo de procesos para la transformación de biomasa en bioenergía. info:eu-repo/semantics/restrictedAccess application/pdf Springer Applied Microbiology and Biotechnology (2020)
spellingShingle Genomas
Glucanos
Isoptera
Identificación
Genomes
Glucans
Identification
Endoglucanases
Termites
Ben Guerrero, Emiliano
Marrero Diaz De Villegas, Ruben
Soria, Marcelo Abel
Santangelo, María De La Paz
Campos, Eleonora
Talia, Paola Mónica
Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title_full Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title_fullStr Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title_full_unstemmed Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title_short Characterization of two GH5 endoglucanases from termite microbiome using synthetic metagenomics
title_sort characterization of two gh5 endoglucanases from termite microbiome using synthetic metagenomics
topic Genomas
Glucanos
Isoptera
Identificación
Genomes
Glucans
Identification
Endoglucanases
Termites
url http://hdl.handle.net/20.500.12123/7767
https://link.springer.com/article/10.1007/s00253-020-10831-5
https://doi.org/10.1007/s00253-020-10831-5
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