Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure

Lettuce (Lactuca sativa L.) is one of the most consumed vegetables worldwide and is considered a good source of healthpromoting compounds. The objective of this work was to apply a multivariate design of experiments through a screening stage followed by optimization of factors that afect the extract...

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Autores principales: Lemos, Aldana Ayelén, Soto Vargas, Verónica Carolina, Wuilloud, Rodolfo Germán, Gonzalez, Roxana Elizabeth
Formato: info:ar-repo/semantics/artículo
Lenguaje:Inglés
Publicado: Springer 2024
Materias:
Acceso en línea:http://hdl.handle.net/20.500.12123/20392
https://link.springer.com/article/10.1007/s12161-024-02656-z
https://doi.org/10.1007/s12161-024-02656-z
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author Lemos, Aldana Ayelén
Soto Vargas, Verónica Carolina
Wuilloud, Rodolfo Germán
Gonzalez, Roxana Elizabeth
author_browse Gonzalez, Roxana Elizabeth
Lemos, Aldana Ayelén
Soto Vargas, Verónica Carolina
Wuilloud, Rodolfo Germán
author_facet Lemos, Aldana Ayelén
Soto Vargas, Verónica Carolina
Wuilloud, Rodolfo Germán
Gonzalez, Roxana Elizabeth
author_sort Lemos, Aldana Ayelén
collection INTA Digital
description Lettuce (Lactuca sativa L.) is one of the most consumed vegetables worldwide and is considered a good source of healthpromoting compounds. The objective of this work was to apply a multivariate design of experiments through a screening stage followed by optimization of factors that afect the extraction of phytochemicals present in lettuce. A response surface methodology was employed and, specifcally, a central composite design model, for the optimization of the methods. The optimal conditions for the extraction of chlorophyll a, b, and total carotenoids were as follows: 4.8 mL of acetone:water (80:20 v/v) and 10 mg of sample with ultrasound-assisted extraction for 5 min. On the other hand, for anthocyanin and phenolic compounds, the optimal conditions were as follows: 5 mL of acetone:acidifed water (80:20 v/v) and 20 mg of sample for 5 min with ultrasound-assisted extraction. The experimental model was followed by spectrophotometry methodology for a comprehensive characterization. Optimal conditions were applied for the simultaneous extraction and determination of the above-mentioned compounds in diferent lettuce cultivars. Both extraction methods successfully extract diferent phytochemicals by reducing the volume of solvent, sample mass, and extraction time compared to previously reported methods. The results obtained showed a signifcant variability in the content of phytochemicals; therefore, it could be estimated that the diferent cultivars of lettuce evaluated will exhibit diferent benefcial health efects.
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spelling INTA203922025-08-19T11:33:47Z Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure Lemos, Aldana Ayelén Soto Vargas, Verónica Carolina Wuilloud, Rodolfo Germán Gonzalez, Roxana Elizabeth Compuestos Bioactivos Lechugas Lactuca sativa Fitoquímicos Diseño Experimental Bioactive Compounds Lettuces Phytochemicals Experimental Design Lactuca sativa L. Quantification Lettuce (Lactuca sativa L.) is one of the most consumed vegetables worldwide and is considered a good source of healthpromoting compounds. The objective of this work was to apply a multivariate design of experiments through a screening stage followed by optimization of factors that afect the extraction of phytochemicals present in lettuce. A response surface methodology was employed and, specifcally, a central composite design model, for the optimization of the methods. The optimal conditions for the extraction of chlorophyll a, b, and total carotenoids were as follows: 4.8 mL of acetone:water (80:20 v/v) and 10 mg of sample with ultrasound-assisted extraction for 5 min. On the other hand, for anthocyanin and phenolic compounds, the optimal conditions were as follows: 5 mL of acetone:acidifed water (80:20 v/v) and 20 mg of sample for 5 min with ultrasound-assisted extraction. The experimental model was followed by spectrophotometry methodology for a comprehensive characterization. Optimal conditions were applied for the simultaneous extraction and determination of the above-mentioned compounds in diferent lettuce cultivars. Both extraction methods successfully extract diferent phytochemicals by reducing the volume of solvent, sample mass, and extraction time compared to previously reported methods. The results obtained showed a signifcant variability in the content of phytochemicals; therefore, it could be estimated that the diferent cultivars of lettuce evaluated will exhibit diferent benefcial health efects. EEA Mendoza Fil: Lemos, Aldana. Universidad Nacional de Cuyo (UNCuyo). Facultad de Ciencias Exactas y Naturales (FCEN). Laboratorio de Química Analítica para Investigación y Desarrollo (QUIANID); Argentina Fil: Lemos, Aldana. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET). Instituto Interdisciplinario de Ciencias Básicas (ICB); Argentina Fil: Lemos, Aldana. Universidad Nacional de Cuyo (UNCuyo). Instituto Interdisciplinario de Ciencias Básicas (ICB); Argentina Fil: Soto Vargas, Verónica Carolina. Universidad Nacional de Cuyo (UNCuyo). Facultad de Ciencias Agrarias (FCA). Instituto de Biología Agrícola de Mendoza (IBAM); Argentina Fil: Soto Vargas, Verónica Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET). Instituto de Biología Agrícola de Mendoza (IBAM); Argentina Fil: Wuilloud, Rodolfo Germán. Universidad Nacional de Cuyo (UNCuyo). Facultad de Ciencias Exactas y Naturales (FCEN). Laboratorio de Química Analítica para Investigación y Desarrollo (QUIANID); Argentina Fil: Wuilloud, Rodolfo Germán. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET). Instituto Interdisciplinario de Ciencias Básicas (ICB); Argentina Fil: Wuilloud, Rodolfo Germán. Universidad Nacional de Cuyo (UNCuyo). Instituto Interdisciplinario de Ciencias Básicas (ICB); Argentina Fil: González, Roxana Elizabeth. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria La Consulta; Argentina Fil: González, Roxana Elizabeth. Universidad Nacional de Cuyo (UNCuyo). Facultad de Ciencias Exactas y Naturales (FCEN); Argentina 2024-11-29T12:39:27Z 2024-11-29T12:39:27Z 2024-08 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://hdl.handle.net/20.500.12123/20392 https://link.springer.com/article/10.1007/s12161-024-02656-z 1936-9751 1936-976X (online) https://doi.org/10.1007/s12161-024-02656-z eng info:eu-repograntAgreement/INTA/2019-PD-E7-I152-001/2019-PD-E7-I152-001/AR./Alimentos nutracéuticos, funcionales o para regímenes especiales. info:eu-repograntAgreement/INTA/2019-PE-E7-I517-001/2019-PE-E7-I517-001, Calidad nutricional y sensorial de alimentos y aptitud tecnológica de materia prima asociada a sistemas y territorios productivos con foco en las demandas del consumidor. info:eu-repo/semantics/restrictedAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf Springer Food Analytical Methods 17 (12) : 1281–1291. (August 2024)
spellingShingle Compuestos Bioactivos
Lechugas
Lactuca sativa
Fitoquímicos
Diseño Experimental
Bioactive Compounds
Lettuces
Phytochemicals
Experimental Design
Lactuca sativa L.
Quantification
Lemos, Aldana Ayelén
Soto Vargas, Verónica Carolina
Wuilloud, Rodolfo Germán
Gonzalez, Roxana Elizabeth
Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title_full Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title_fullStr Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title_full_unstemmed Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title_short Screening of bioactive compounds in lettuce: multivariate optimization of an ultrasound‑assisted solid–liquid extraction procedure
title_sort screening of bioactive compounds in lettuce multivariate optimization of an ultrasound assisted solid liquid extraction procedure
topic Compuestos Bioactivos
Lechugas
Lactuca sativa
Fitoquímicos
Diseño Experimental
Bioactive Compounds
Lettuces
Phytochemicals
Experimental Design
Lactuca sativa L.
Quantification
url http://hdl.handle.net/20.500.12123/20392
https://link.springer.com/article/10.1007/s12161-024-02656-z
https://doi.org/10.1007/s12161-024-02656-z
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