Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)

The aim of this study was to determine and compare the melting (Tm), glass transition (Tg) and mechanical relaxation (Tα) temperatures of a new waxy cassava starch. Thermal transitions measurements were obtained by Differential Scanning Calorimetry (DSC) and Dynamical Mechanical Thermal Analysis (DM...

Descripción completa

Detalles Bibliográficos
Autores principales: Pulido Diaz, Adriana, Lourdin, Denis, Della Valle, Guy, Fernández Quintero, Alejandro, Ceballos, H., Tran, Thierry, Dufour, D.L.
Formato: Journal Article
Lenguaje:Inglés
Publicado: Elsevier 2017
Materias:
Acceso en línea:https://hdl.handle.net/10568/77842
_version_ 1855539117517963264
author Pulido Diaz, Adriana
Lourdin, Denis
Della Valle, Guy
Fernández Quintero, Alejandro
Ceballos, H.
Tran, Thierry
Dufour, D.L.
author_browse Ceballos, H.
Della Valle, Guy
Dufour, D.L.
Fernández Quintero, Alejandro
Lourdin, Denis
Pulido Diaz, Adriana
Tran, Thierry
author_facet Pulido Diaz, Adriana
Lourdin, Denis
Della Valle, Guy
Fernández Quintero, Alejandro
Ceballos, H.
Tran, Thierry
Dufour, D.L.
author_sort Pulido Diaz, Adriana
collection Repository of Agricultural Research Outputs (CGSpace)
description The aim of this study was to determine and compare the melting (Tm), glass transition (Tg) and mechanical relaxation (Tα) temperatures of a new waxy cassava starch. Thermal transitions measurements were obtained by Differential Scanning Calorimetry (DSC) and Dynamical Mechanical Thermal Analysis (DMTA). The experimental data showed a high correlation between water volume fraction and melting temperature (Tm) indicating that the Flory-Huggins theory can be used to describe the thermal behavior of this starch. The Tm of waxy cassava starch-water mixes were lower than a waxy corn starch-water reference system, but differences were not statistically significant. The mechanical relaxation temperatures taken at tan δ peaks were found 29–38 °C larger than Tg. The Tα and Tg measured for waxy cassava starch exhibited similar properties to the ones of waxy corn starch, implying that waxy cassava starch can be used in food and materials industry.
format Journal Article
id CGSpace77842
institution CGIAR Consortium
language Inglés
publishDate 2017
publishDateRange 2017
publishDateSort 2017
publisher Elsevier
publisherStr Elsevier
record_format dspace
spelling CGSpace778422025-11-12T05:59:22Z Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz) Pulido Diaz, Adriana Lourdin, Denis Della Valle, Guy Fernández Quintero, Alejandro Ceballos, H. Tran, Thierry Dufour, D.L. amylopectin melting starch manihot esculenta extrusion gelatinization thermal analysis amilopectina fusión almidón extrusión gelificación análisis térmico The aim of this study was to determine and compare the melting (Tm), glass transition (Tg) and mechanical relaxation (Tα) temperatures of a new waxy cassava starch. Thermal transitions measurements were obtained by Differential Scanning Calorimetry (DSC) and Dynamical Mechanical Thermal Analysis (DMTA). The experimental data showed a high correlation between water volume fraction and melting temperature (Tm) indicating that the Flory-Huggins theory can be used to describe the thermal behavior of this starch. The Tm of waxy cassava starch-water mixes were lower than a waxy corn starch-water reference system, but differences were not statistically significant. The mechanical relaxation temperatures taken at tan δ peaks were found 29–38 °C larger than Tg. The Tα and Tg measured for waxy cassava starch exhibited similar properties to the ones of waxy corn starch, implying that waxy cassava starch can be used in food and materials industry. 2017-02 2016-11-22T18:32:16Z 2016-11-22T18:32:16Z Journal Article https://hdl.handle.net/10568/77842 en Open Access application/pdf Elsevier Pulido Diaz, Adriana; Lourdin, Denis; Della Valle, Guy; Fernandez Quintero, Alejandro; Ceballos, Hernán; Tran, Thierry; Dufour, Dominique. 2016. Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz) . Carbohydrate Polymers 157: 1777-1784.
spellingShingle amylopectin
melting
starch
manihot esculenta
extrusion
gelatinization
thermal analysis
amilopectina
fusión
almidón
extrusión
gelificación
análisis térmico
Pulido Diaz, Adriana
Lourdin, Denis
Della Valle, Guy
Fernández Quintero, Alejandro
Ceballos, H.
Tran, Thierry
Dufour, D.L.
Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title_full Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title_fullStr Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title_full_unstemmed Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title_short Thermomechanical characterization of an amylose-free starch extracted from cassava (Manihot esculenta, Crantz)
title_sort thermomechanical characterization of an amylose free starch extracted from cassava manihot esculenta crantz
topic amylopectin
melting
starch
manihot esculenta
extrusion
gelatinization
thermal analysis
amilopectina
fusión
almidón
extrusión
gelificación
análisis térmico
url https://hdl.handle.net/10568/77842
work_keys_str_mv AT pulidodiazadriana thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT lourdindenis thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT dellavalleguy thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT fernandezquinteroalejandro thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT ceballosh thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT tranthierry thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz
AT dufourdl thermomechanicalcharacterizationofanamylosefreestarchextractedfromcassavamanihotesculentacrantz