Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system

BACKGROUND: The isosteric heat of desorption is vital in evaluating the energy performance of food dryers. The isosteric heat of desorption was investigated for different cassava (Manihot esculenta Crantz) products prepared as flour or starch, with and without fermentation. An automated moisture sor...

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Main Authors: Sarnavi, Hamed J., Precoppe, Marcelo, García Triñanes, Pablo, Chapuis, Arnaud, Tran, Thierry, Bradley, Michael S.A., Müller, Joachim
Format: Journal Article
Language:Inglés
Published: Wiley 2023
Subjects:
Online Access:https://hdl.handle.net/10568/128355
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author Sarnavi, Hamed J.
Precoppe, Marcelo
García Triñanes, Pablo
Chapuis, Arnaud
Tran, Thierry
Bradley, Michael S.A.
Müller, Joachim
author_browse Bradley, Michael S.A.
Chapuis, Arnaud
García Triñanes, Pablo
Müller, Joachim
Precoppe, Marcelo
Sarnavi, Hamed J.
Tran, Thierry
author_facet Sarnavi, Hamed J.
Precoppe, Marcelo
García Triñanes, Pablo
Chapuis, Arnaud
Tran, Thierry
Bradley, Michael S.A.
Müller, Joachim
author_sort Sarnavi, Hamed J.
collection Repository of Agricultural Research Outputs (CGSpace)
description BACKGROUND: The isosteric heat of desorption is vital in evaluating the energy performance of food dryers. The isosteric heat of desorption was investigated for different cassava (Manihot esculenta Crantz) products prepared as flour or starch, with and without fermentation. An automated moisture sorption gravimetric analyser was used to measure the desorption isotherms over 10–90% relative humidity of the drying air at temperatures ranging from 25 to 65 °C. RESULTS: Analysis of variance showed an imperceptible contribution of the preparation method in the measured desorption data. This finding also agreed with microscopical images, which revealed the lack of compelling structural differences among different products. A set of empirical sorption equations suggested by the ASAE standard was examined over the measured desorption isotherms. The standard error of estimation was found to be in the acceptable range of 2.36–3.71%. Furthermore, the fulfilment of the enthalpy-entropy compensation theory was considered as an additional criterion in the thermodynamic results of different sorption equations, besides their fitting adequacy. The modified Chung–Pfost equation has proved to be the most suitable equation for cassava products, as it is capable of reflecting the temperature dependency of the isosteric heat of desorption. The net isosteric heat of desorption obtained was in the range of 540–1110 kJ kg−1 for 0.10 kg kg−1 dry-basis moisture content and 52–108 kJ kg−1 for 0.25 kg kg−1 dry-basis moisture content.
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spelling CGSpace1283552025-10-26T12:51:25Z Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system Sarnavi, Hamed J. Precoppe, Marcelo García Triñanes, Pablo Chapuis, Arnaud Tran, Thierry Bradley, Michael S.A. Müller, Joachim starch sorption drying flours efficiency isothermal processes cassava food science biotechnology BACKGROUND: The isosteric heat of desorption is vital in evaluating the energy performance of food dryers. The isosteric heat of desorption was investigated for different cassava (Manihot esculenta Crantz) products prepared as flour or starch, with and without fermentation. An automated moisture sorption gravimetric analyser was used to measure the desorption isotherms over 10–90% relative humidity of the drying air at temperatures ranging from 25 to 65 °C. RESULTS: Analysis of variance showed an imperceptible contribution of the preparation method in the measured desorption data. This finding also agreed with microscopical images, which revealed the lack of compelling structural differences among different products. A set of empirical sorption equations suggested by the ASAE standard was examined over the measured desorption isotherms. The standard error of estimation was found to be in the acceptable range of 2.36–3.71%. Furthermore, the fulfilment of the enthalpy-entropy compensation theory was considered as an additional criterion in the thermodynamic results of different sorption equations, besides their fitting adequacy. The modified Chung–Pfost equation has proved to be the most suitable equation for cassava products, as it is capable of reflecting the temperature dependency of the isosteric heat of desorption. The net isosteric heat of desorption obtained was in the range of 540–1110 kJ kg−1 for 0.10 kg kg−1 dry-basis moisture content and 52–108 kJ kg−1 for 0.25 kg kg−1 dry-basis moisture content. 2023-01-15 2023-01-31T10:23:33Z 2023-01-31T10:23:33Z Journal Article https://hdl.handle.net/10568/128355 en Open Access Wiley Sarnavi, H.J.; Precoppe, M.; García-Triñanes, P.; Chapuis, A.; Tran, T.; Bradley, M.S.A. and Müller, J. 2023. Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system. Journal of The Science of Food and Agriculture 103(1):389-399. ISSN: 1097-0010
spellingShingle starch
sorption
drying
flours
efficiency
isothermal processes
cassava
food science
biotechnology
Sarnavi, Hamed J.
Precoppe, Marcelo
García Triñanes, Pablo
Chapuis, Arnaud
Tran, Thierry
Bradley, Michael S.A.
Müller, Joachim
Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title_full Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title_fullStr Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title_full_unstemmed Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title_short Determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
title_sort determining the heat of desorption for cassava products based on data measured by an automated gravimetric moisture sorption system
topic starch
sorption
drying
flours
efficiency
isothermal processes
cassava
food science
biotechnology
url https://hdl.handle.net/10568/128355
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