Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining

In response to the growing numbers of contaminated sites, concerns about proper management with reduced environmental footprints have been raised. In the present study, mining of highly contaminated sediments to recover valuable elements such as metals and nutrients is proposed as sustainable approa...

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Autor principal: Fathollahzadeh, Homayoun
Formato: H2
Lenguaje:Inglés
Publicado: SLU/Dept. of Aquatic Sciences and Assessment 2013
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author Fathollahzadeh, Homayoun
author_browse Fathollahzadeh, Homayoun
author_facet Fathollahzadeh, Homayoun
author_sort Fathollahzadeh, Homayoun
collection Epsilon Archive for Student Projects
description In response to the growing numbers of contaminated sites, concerns about proper management with reduced environmental footprints have been raised. In the present study, mining of highly contaminated sediments to recover valuable elements such as metals and nutrients is proposed as sustainable approach, both through enhancing resilience of ecosystems and remediation, beside probable turnovers. Thereby, in order to evaluate feasibility of metal recovery, fractionation of thirteen heavy and trace metals (Fe, Al, As, Ba, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Zn) in Oskarshamn harbor and Malmfjärden semi-enclosed bay surface sediments taken from five polluted locations in Kalmar County in southeast of Sweden was studied. The dissolution experiment by a modified BCR (Community Bureau of Reference, now SM&T) sequential extraction procedure (BCR-SEP) was used to determine the partitioning of elements. Oskarshamn and Malmfjärden sediments showed highest mobility for Zn and Cd, which can be leached out easily by small changes in environment conditions, whereas Al, Ba, and Hg in both sites, beside Cr and Fe in Malmfjärden exhibited high percentage in residual fraction. Moreover, total digestion results turn out that Oskarshamn in comparing to Malmfjärden sediments tended to result in larger contents of total extractable heavy metals (except Al), which is strongly attributed to factories, wastewater treatment plants, and ships traffic in Oskarshamn basin and diffusive sources in Malmfjärden. Despite the smaller magnitude of pollution in Malmfjärden relative to Oskarshamn, besides dredging and removal of sediments, in situ remediation techniques such as capping, using amendments and phytoremediation could be suggested. The results indicated that among different metals in the sediments, particularly in Oskarshamn, Cu and Pb followed by As, Cr and Ni can be considered for future sediment mining.
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spelling RepoSLU53412013-03-12T11:19:42Z Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining Fathollahzadeh, Homayoun Sediment mining harbor semi-enclosed bay speciation metals sequential extraction procedure recovery sustainable environmental footprint environmental assessment In response to the growing numbers of contaminated sites, concerns about proper management with reduced environmental footprints have been raised. In the present study, mining of highly contaminated sediments to recover valuable elements such as metals and nutrients is proposed as sustainable approach, both through enhancing resilience of ecosystems and remediation, beside probable turnovers. Thereby, in order to evaluate feasibility of metal recovery, fractionation of thirteen heavy and trace metals (Fe, Al, As, Ba, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Zn) in Oskarshamn harbor and Malmfjärden semi-enclosed bay surface sediments taken from five polluted locations in Kalmar County in southeast of Sweden was studied. The dissolution experiment by a modified BCR (Community Bureau of Reference, now SM&T) sequential extraction procedure (BCR-SEP) was used to determine the partitioning of elements. Oskarshamn and Malmfjärden sediments showed highest mobility for Zn and Cd, which can be leached out easily by small changes in environment conditions, whereas Al, Ba, and Hg in both sites, beside Cr and Fe in Malmfjärden exhibited high percentage in residual fraction. Moreover, total digestion results turn out that Oskarshamn in comparing to Malmfjärden sediments tended to result in larger contents of total extractable heavy metals (except Al), which is strongly attributed to factories, wastewater treatment plants, and ships traffic in Oskarshamn basin and diffusive sources in Malmfjärden. Despite the smaller magnitude of pollution in Malmfjärden relative to Oskarshamn, besides dredging and removal of sediments, in situ remediation techniques such as capping, using amendments and phytoremediation could be suggested. The results indicated that among different metals in the sediments, particularly in Oskarshamn, Cu and Pb followed by As, Cr and Ni can be considered for future sediment mining. SLU/Dept. of Aquatic Sciences and Assessment 2013 H2 eng https://stud.epsilon.slu.se/5341/
spellingShingle Sediment mining
harbor
semi-enclosed bay
speciation
metals
sequential extraction procedure
recovery
sustainable
environmental footprint
environmental assessment
Fathollahzadeh, Homayoun
Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title_full Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title_fullStr Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title_full_unstemmed Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title_short Speciation of metals in contaminated sediments in the Kalmar County, Sweden : an initial approach toward sediment mining
title_sort speciation of metals in contaminated sediments in the kalmar county, sweden : an initial approach toward sediment mining
topic Sediment mining
harbor
semi-enclosed bay
speciation
metals
sequential extraction procedure
recovery
sustainable
environmental footprint
environmental assessment