Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils

Engineered nanoparticles (ENPs) are used in so many different products. ENPs are released into different environmental compartments. Silver nanoparticle (AgNP) is one of the most used ENPs. AgNPs may cause damage to the environment due to their toxicity and wide exposure. In this thesis possible...

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Autor principal: Geranmayeh Oromieh, Aidin
Formato: Second cycle, A2E
Lenguaje:Inglés
Inglés
Publicado: 2011
Materias:
Acceso en línea:https://stud.epsilon.slu.se/2358/
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author Geranmayeh Oromieh, Aidin
author_browse Geranmayeh Oromieh, Aidin
author_facet Geranmayeh Oromieh, Aidin
author_sort Geranmayeh Oromieh, Aidin
collection Epsilon Archive for Student Projects
description Engineered nanoparticles (ENPs) are used in so many different products. ENPs are released into different environmental compartments. Silver nanoparticle (AgNP) is one of the most used ENPs. AgNPs may cause damage to the environment due to their toxicity and wide exposure. In this thesis possible exposure ways of AgNPs to the environment was reported. Also sorption-solubility and aggregation of AgNPs and AgNO3 based on the different concentration of Ag and pH function in clayey and sandy soil was investigated. Results showed that sorption of both silver nanoparticles and silver ions by the soils were increased with increasing pH. Silver (nano/ion) sorption ratio in clayey treatment was slightly higher than sandy one. It can be due to having higher CEC value and finer texture in clay in comparison with sand. Partitioning between nanosilver and free silver ions was investigated by help of ultrafiltration. It can be concluded that a significant fraction of the silver nanoparticles were oxidized and transformed to free Ag+ during the oxic experimental conditions. The aggregation of AgNPs and silver ions was investigated based on the different concentration of silver in a constant pH. Aggregation of silver nanoparticulate by help of SEM and XRD were identified in 2.5 ppm concentration of AgNPs in sandy soil. No aggregation was found at low concentration of silver nanoparticles. No silver aggregated spot could be recognized at 6.7, 0.65 and 0.05 ppm concentration of silver in silver nitrate polluted soil samples.
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Inglés
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spelling RepoSLU23582012-10-06T15:50:17Z https://stud.epsilon.slu.se/2358/ Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils Geranmayeh Oromieh, Aidin Soil science and management Soil chemistry and physics Pollution Engineered nanoparticles (ENPs) are used in so many different products. ENPs are released into different environmental compartments. Silver nanoparticle (AgNP) is one of the most used ENPs. AgNPs may cause damage to the environment due to their toxicity and wide exposure. In this thesis possible exposure ways of AgNPs to the environment was reported. Also sorption-solubility and aggregation of AgNPs and AgNO3 based on the different concentration of Ag and pH function in clayey and sandy soil was investigated. Results showed that sorption of both silver nanoparticles and silver ions by the soils were increased with increasing pH. Silver (nano/ion) sorption ratio in clayey treatment was slightly higher than sandy one. It can be due to having higher CEC value and finer texture in clay in comparison with sand. Partitioning between nanosilver and free silver ions was investigated by help of ultrafiltration. It can be concluded that a significant fraction of the silver nanoparticles were oxidized and transformed to free Ag+ during the oxic experimental conditions. The aggregation of AgNPs and silver ions was investigated based on the different concentration of silver in a constant pH. Aggregation of silver nanoparticulate by help of SEM and XRD were identified in 2.5 ppm concentration of AgNPs in sandy soil. No aggregation was found at low concentration of silver nanoparticles. No silver aggregated spot could be recognized at 6.7, 0.65 and 0.05 ppm concentration of silver in silver nitrate polluted soil samples. 2011-03-15 Second cycle, A2E NonPeerReviewed application/pdf eng https://stud.epsilon.slu.se/2358/1/geranmayeh_oromieh_a_110315.pdf Geranmayeh Oromieh, Aidin, 2011. Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils. Second cycle, A2E. Uppsala: (NL, NJ) > Dept. of Soil and Environment <https://stud.epsilon.slu.se/view/divisions/OID-435.html> urn:nbn:se:slu:epsilon-8-1018 eng
spellingShingle Soil science and management
Soil chemistry and physics
Pollution
Geranmayeh Oromieh, Aidin
Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title_full Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title_fullStr Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title_full_unstemmed Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title_short Evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
title_sort evaluating solubility, aggregation and sorption of nanosilver particles and silver ions in soils
topic Soil science and management
Soil chemistry and physics
Pollution
url https://stud.epsilon.slu.se/2358/
https://stud.epsilon.slu.se/2358/