Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina

In soils of semi-arid regions, different amounts of glyphosate are applied, and this substance tends to be absorbed on the topsoil exposed to erosion. The objective of this study was to analyze the effects of land management on the concentration of glyphosate and AMPA in the respirable dust emitted...

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Autores principales: Ramirez Haberkon, Nancy, Aimar, Silvia Beatriz, Aparicio, Virginia Carolina, Buschiazzo, Daniel Eduardo, De Geronimo, Eduardo, Costa, Jose Luis, Mendez, Mariano
Formato: info:ar-repo/semantics/artículo
Lenguaje:Inglés
Publicado: Elsevier 2020
Materias:
Acceso en línea:http://hdl.handle.net/20.500.12123/8452
https://www.sciencedirect.com/science/article/abs/pii/S1875963720301105
https://doi.org/10.1016/j.aeolia.2020.100658
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author Ramirez Haberkon, Nancy
Aimar, Silvia Beatriz
Aparicio, Virginia Carolina
Buschiazzo, Daniel Eduardo
De Geronimo, Eduardo
Costa, Jose Luis
Mendez, Mariano
author_browse Aimar, Silvia Beatriz
Aparicio, Virginia Carolina
Buschiazzo, Daniel Eduardo
Costa, Jose Luis
De Geronimo, Eduardo
Mendez, Mariano
Ramirez Haberkon, Nancy
author_facet Ramirez Haberkon, Nancy
Aimar, Silvia Beatriz
Aparicio, Virginia Carolina
Buschiazzo, Daniel Eduardo
De Geronimo, Eduardo
Costa, Jose Luis
Mendez, Mariano
author_sort Ramirez Haberkon, Nancy
collection INTA Digital
description In soils of semi-arid regions, different amounts of glyphosate are applied, and this substance tends to be absorbed on the topsoil exposed to erosion. The objective of this study was to analyze the effects of land management on the concentration of glyphosate and AMPA in the respirable dust emitted by soils in the central semi-arid region of Argentina. Soil samples were collected from nine agricultural soils under no-tillage with genetically modified Annual crops (AG), five agricultural soils under conventional tillage with annual crops (non-glyphosate-resistant) (AFG), and two permanent grasses (PG) with no-tillage and no glyphosate application in the last 30 years. The particulate matter finer than 10 µm in diameter (PM10) was generated and collected from each soil by means of an electrostatic dust sampler. Glyphosate and AMPA were analyzed in the soils and PM10. The percentage of detection (number of samples with glyphosate/AMPA over the total number of samples analyzed) was calculated. AG had the highest glyphosate and AMPA percentage of detection, in both, soil and PM10 (100% in all cases). Similar results were found for AFG, except for glyphosate in soil, where the percentage of detection was 80%. In PG, no glyphosate was detected in soil but it was detected in 83% of the PM10 samples. AMPA was detected in 67% and 100% of soil and PM10 samples, respectively. The detection in PG suggests the entry of glyphosate and AMPA from other sites. The contents of glyphosate and AMPA in soil and PM10 were greater in AG than in AFG and PG. In soil, the content of glyphosate was 69 µg kg−1 in AG and 5 µg kg−1 in AFG. In PM10, the content of glyphosate was 224 µg kg−1 in AG, 25 µg kg−1 in AFG, and 35 µg kg−1 in PG. AMPA showed a similar behavior to glyphosate in both soil and PM10. The greater use of glyphosate in AG increases the concentration of glyphosate and AMPA in soil and PM10. It determines an increase in environmental risk when wind erosion events occur in AG. In all management systems analyzed, AMPA content was greater than glyphosate content, and glyphosate and AMPA contents in PM10 were higher than those in soil. This result shows the potential risk posed by PM10 emitted from agricultural soil to human health and the environment. To our knowledge, this is the first study that shows how land management affects the occurrence and concentration of glyphosate and AMPA in PM10.
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spelling INTA84522025-03-07T17:09:25Z Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina Ramirez Haberkon, Nancy Aimar, Silvia Beatriz Aparicio, Virginia Carolina Buschiazzo, Daniel Eduardo De Geronimo, Eduardo Costa, Jose Luis Mendez, Mariano Manejo del Suelo Glifosato Ordenación de Tierras Polvo (contaminante) Argentina Soil Management Glyphosate Land Management In soils of semi-arid regions, different amounts of glyphosate are applied, and this substance tends to be absorbed on the topsoil exposed to erosion. The objective of this study was to analyze the effects of land management on the concentration of glyphosate and AMPA in the respirable dust emitted by soils in the central semi-arid region of Argentina. Soil samples were collected from nine agricultural soils under no-tillage with genetically modified Annual crops (AG), five agricultural soils under conventional tillage with annual crops (non-glyphosate-resistant) (AFG), and two permanent grasses (PG) with no-tillage and no glyphosate application in the last 30 years. The particulate matter finer than 10 µm in diameter (PM10) was generated and collected from each soil by means of an electrostatic dust sampler. Glyphosate and AMPA were analyzed in the soils and PM10. The percentage of detection (number of samples with glyphosate/AMPA over the total number of samples analyzed) was calculated. AG had the highest glyphosate and AMPA percentage of detection, in both, soil and PM10 (100% in all cases). Similar results were found for AFG, except for glyphosate in soil, where the percentage of detection was 80%. In PG, no glyphosate was detected in soil but it was detected in 83% of the PM10 samples. AMPA was detected in 67% and 100% of soil and PM10 samples, respectively. The detection in PG suggests the entry of glyphosate and AMPA from other sites. The contents of glyphosate and AMPA in soil and PM10 were greater in AG than in AFG and PG. In soil, the content of glyphosate was 69 µg kg−1 in AG and 5 µg kg−1 in AFG. In PM10, the content of glyphosate was 224 µg kg−1 in AG, 25 µg kg−1 in AFG, and 35 µg kg−1 in PG. AMPA showed a similar behavior to glyphosate in both soil and PM10. The greater use of glyphosate in AG increases the concentration of glyphosate and AMPA in soil and PM10. It determines an increase in environmental risk when wind erosion events occur in AG. In all management systems analyzed, AMPA content was greater than glyphosate content, and glyphosate and AMPA contents in PM10 were higher than those in soil. This result shows the potential risk posed by PM10 emitted from agricultural soil to human health and the environment. To our knowledge, this is the first study that shows how land management affects the occurrence and concentration of glyphosate and AMPA in PM10. EEA Balcarce Fil: Ramirez Haberkon, Nancy . Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Aimar, Silvia. Universidad Nacional de La Pampa. Facultad de Agronomía; Argentina Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Buschiazzo, Daniel Eduardo. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa. Facultad de Agronomía; Argentina Fil: De Gerónimo, Eduardo Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Mendez, Mariano. Instituto de Ciencias de la Tierra y Ambientales de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Pampa. Facultad de Agronomía; Argentina 2020-12-17T13:45:14Z 2020-12-17T13:45:14Z 2020-12 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://hdl.handle.net/20.500.12123/8452 https://www.sciencedirect.com/science/article/abs/pii/S1875963720301105 1875-9637 https://doi.org/10.1016/j.aeolia.2020.100658 eng info:eu-repo/semantics/restrictedAccess application/pdf Elsevier Aeolian Research 49 : 100658 (2021)
spellingShingle Manejo del Suelo
Glifosato
Ordenación de Tierras
Polvo (contaminante)
Argentina
Soil Management
Glyphosate
Land Management
Ramirez Haberkon, Nancy
Aimar, Silvia Beatriz
Aparicio, Virginia Carolina
Buschiazzo, Daniel Eduardo
De Geronimo, Eduardo
Costa, Jose Luis
Mendez, Mariano
Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title_full Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title_fullStr Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title_full_unstemmed Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title_short Management effects on glyphosate and AMPA concentrations in the PM10 emitted by soils of the central semi-arid region of Argentina
title_sort management effects on glyphosate and ampa concentrations in the pm10 emitted by soils of the central semi arid region of argentina
topic Manejo del Suelo
Glifosato
Ordenación de Tierras
Polvo (contaminante)
Argentina
Soil Management
Glyphosate
Land Management
url http://hdl.handle.net/20.500.12123/8452
https://www.sciencedirect.com/science/article/abs/pii/S1875963720301105
https://doi.org/10.1016/j.aeolia.2020.100658
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