High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface

The effect of using increasing proportions of methylcellulose (MC) for the development of glycerol plasticized films based on high methoxyl pectin (HMP) (30:70, 50:50 and 70:30 w/w HMP:MC) and carrying l-(+)-ascorbic acid (AA) was studied with the purpose of achieving higher stability of AA and loca...

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Autores principales: Perez, Carolina Daiana, De'Nobili, Maria Dolores, Rizzo, Sergio Anibal, Gerschenson, Lia Noemi, Descalzo, Adriana Maria, Rojas, Ana Maria Luisa
Formato: Artículo
Lenguaje:Inglés
Publicado: 2018
Materias:
Acceso en línea:https://www.sciencedirect.com/science/article/pii/S0260877412005560
http://hdl.handle.net/20.500.12123/2712
https://doi.org/10.1016/j.jfoodeng.2012.11.004
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author Perez, Carolina Daiana
De'Nobili, Maria Dolores
Rizzo, Sergio Anibal
Gerschenson, Lia Noemi
Descalzo, Adriana Maria
Rojas, Ana Maria Luisa
author_browse De'Nobili, Maria Dolores
Descalzo, Adriana Maria
Gerschenson, Lia Noemi
Perez, Carolina Daiana
Rizzo, Sergio Anibal
Rojas, Ana Maria Luisa
author_facet Perez, Carolina Daiana
De'Nobili, Maria Dolores
Rizzo, Sergio Anibal
Gerschenson, Lia Noemi
Descalzo, Adriana Maria
Rojas, Ana Maria Luisa
author_sort Perez, Carolina Daiana
collection INTA Digital
description The effect of using increasing proportions of methylcellulose (MC) for the development of glycerol plasticized films based on high methoxyl pectin (HMP) (30:70, 50:50 and 70:30 w/w HMP:MC) and carrying l-(+)-ascorbic acid (AA) was studied with the purpose of achieving higher stability of AA and localized antioxidant activity at food interfaces. MC and 30:70 HMP:MC systems could not be casted. The shelf-life of the other AA-active films was assessed by storage at 25 °C, constant relative humidity (RH: 33.3%, 57.7% and 75.2%) and vacuum conditions. The rate constant for AA hydrolysis increased with the RH and, hence, with water mobility. Browning and AA degradation rates were directly related. When stored at 75.2% RH, both decreased as MC proportion increased. Compared to HMP film, the highest proportion of MC (50:50 HMP:MC) showed the highest AA stabilization under vacuum and greater performance under air atmosphere. They also developed localized antioxidant activity preserving the tocopherol content of walnut oil.
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spelling INTA27122018-07-03T13:25:16Z High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface Perez, Carolina Daiana De'Nobili, Maria Dolores Rizzo, Sergio Anibal Gerschenson, Lia Noemi Descalzo, Adriana Maria Rojas, Ana Maria Luisa Nuez Aceites Metilcelulosa Pectinas Acido Ascórbico Walnuts Oils Methyl Cellulose Pectins Ascorbic Acid Film The effect of using increasing proportions of methylcellulose (MC) for the development of glycerol plasticized films based on high methoxyl pectin (HMP) (30:70, 50:50 and 70:30 w/w HMP:MC) and carrying l-(+)-ascorbic acid (AA) was studied with the purpose of achieving higher stability of AA and localized antioxidant activity at food interfaces. MC and 30:70 HMP:MC systems could not be casted. The shelf-life of the other AA-active films was assessed by storage at 25 °C, constant relative humidity (RH: 33.3%, 57.7% and 75.2%) and vacuum conditions. The rate constant for AA hydrolysis increased with the RH and, hence, with water mobility. Browning and AA degradation rates were directly related. When stored at 75.2% RH, both decreased as MC proportion increased. Compared to HMP film, the highest proportion of MC (50:50 HMP:MC) showed the highest AA stabilization under vacuum and greater performance under air atmosphere. They also developed localized antioxidant activity preserving the tocopherol content of walnut oil. Instituto de Tecnología de Alimentos Fil: Perez, Carolina Daiana. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina Fil: De'nobili, Maria Dolores. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Rizzo, Sergio Anibal. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Tecnología de Alimentos; Argentina Fil: Gerschenson, Lia Noemi. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Descalzo, Adriana Maria. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Tecnología de Alimentos; Argentina Fil: Rojas, Ana Maria Luisa. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina 2018-07-03T13:23:55Z 2018-07-03T13:23:55Z 2013-05 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion https://www.sciencedirect.com/science/article/pii/S0260877412005560 http://hdl.handle.net/20.500.12123/2712 0260-8774 https://doi.org/10.1016/j.jfoodeng.2012.11.004 eng info:eu-repo/semantics/restrictedAccess application/pdf Journal of Food Engineering 116 (1) : 162-169 (May 2013)
spellingShingle Nuez
Aceites
Metilcelulosa
Pectinas
Acido Ascórbico
Walnuts
Oils
Methyl Cellulose
Pectins
Ascorbic Acid
Film
Perez, Carolina Daiana
De'Nobili, Maria Dolores
Rizzo, Sergio Anibal
Gerschenson, Lia Noemi
Descalzo, Adriana Maria
Rojas, Ana Maria Luisa
High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title_full High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title_fullStr High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title_full_unstemmed High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title_short High methoxyl pectin–methyl cellulose films with antioxidant activity at a functional food interface
title_sort high methoxyl pectin methyl cellulose films with antioxidant activity at a functional food interface
topic Nuez
Aceites
Metilcelulosa
Pectinas
Acido Ascórbico
Walnuts
Oils
Methyl Cellulose
Pectins
Ascorbic Acid
Film
url https://www.sciencedirect.com/science/article/pii/S0260877412005560
http://hdl.handle.net/20.500.12123/2712
https://doi.org/10.1016/j.jfoodeng.2012.11.004
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