Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production

The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas st...

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Main Authors: Van Opstal, Natalia Veronica, Gabioud, Emmanuel Adrian, Seehaus, Mariela, Pighini, Ramiro Joaquin, Repetti, Maria Rosa, Wilson, Marcelo German, Wingeyer, Ana Beatriz, Cuatrin, Alejandra, Regaldo, Luciana Maria, Gagneten, Ana Maria, Sasal, Maria Carolina
Format: Artículo
Language:Inglés
Published: Springer 2023
Subjects:
Online Access:http://hdl.handle.net/20.500.12123/13921
https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/
https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004
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author Van Opstal, Natalia Veronica
Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
author_browse Cuatrin, Alejandra
Gabioud, Emmanuel Adrian
Gagneten, Ana Maria
Pighini, Ramiro Joaquin
Regaldo, Luciana Maria
Repetti, Maria Rosa
Sasal, Maria Carolina
Seehaus, Mariela
Van Opstal, Natalia Veronica
Wilson, Marcelo German
Wingeyer, Ana Beatriz
author_facet Van Opstal, Natalia Veronica
Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
author_sort Van Opstal, Natalia Veronica
collection INTA Digital
description The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.
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spelling INTA139212023-02-13T12:52:22Z Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production Van Opstal, Natalia Veronica Gabioud, Emmanuel Adrian Seehaus, Mariela Pighini, Ramiro Joaquin Repetti, Maria Rosa Wilson, Marcelo German Wingeyer, Ana Beatriz Cuatrin, Alejandra Regaldo, Luciana Maria Gagneten, Ana Maria Sasal, Maria Carolina Pesticides Watersheds Surface Water Environmental Monitoring Plaguicidas Cuencas Hidrográficas Agua Superficial Vigilancia Ambiental Entre Ríos Arroyo Estacas Estacas Stream The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins. EEA Paraná Fil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina Fil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina Fil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina 2023-01-23T14:12:08Z 2023-01-23T14:12:08Z 2023-01 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://hdl.handle.net/20.500.12123/13921 https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/ Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-2 1614-7499 https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004 eng info:eu-repograntAgreement/INTA/2019-PD-E2-I039-002/2019-PD-E2-I039-002/AR./REMEDIACIÓN DE SUELOS Y AGUAS Y RESTAURACIÓN ECOLÓGICA DE SISTEMAS DEGRADADOS POR USO AGROPECUARIO, AGROINDUSTRIAL Y ACTIVIDADES EXTRACTIVAS info:eu-repograntAgreement/INTA/2019-PE-E2-I046-001/2019-PE-E2-I046-001/AR./Evaluación de la dinámica de la sostenibilidad de territorios y sistemas de producción. Indicadores info:eu-repograntAgreement/INTA/2019-PE-E2-I041-001/2019-PE-E2-I041-001/AR./Aportes para la gestión integrada de los recursos hídricos (GIRH) en cuencas del Sistema Agroalimentario Argentino info:eu-repo/semantics/restrictedAccess application/pdf Entre Ríos .......... (province) (World, South America, Argentina) 1001237 Springer Environmental science and pollution research (20 January 2023)
spellingShingle Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
Van Opstal, Natalia Veronica
Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_full Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_fullStr Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_full_unstemmed Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_short Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_sort spatial distribution of pesticides in surface water of the estacas stream argentine espinal region associated with crop production
topic Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
url http://hdl.handle.net/20.500.12123/13921
https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/
https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004
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