Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll

Retention is one of the processes controlling the behavior and fate of pesticides in soil. The objective of this work was to evaluate the adsorption and desorption of glyphosate, AMPA, and metsulfuron-methyl in the main horizons of a Typic Argiudoll destined for agricultural use. For this purpose, t...

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Main Authors: Gonzalo Mayoral, Eliana Soledad, Aparicio, Virginia Carolina, De Geronimo, Eduardo, Fernandes, Gracieli, Dos Santos, Danilo Rheinheimer, Costa, José Luis
Format: info:ar-repo/semantics/artículo
Language:Inglés
Published: Taylor and Francis 2022
Subjects:
Online Access:http://hdl.handle.net/20.500.12123/12149
https://www.tandfonline.com/doi/abs/10.1080/03601234.2022.2069982
https://doi.org/10.1080/03601234.2022.2069982
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author Gonzalo Mayoral, Eliana Soledad
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Fernandes, Gracieli
Dos Santos, Danilo Rheinheimer
Costa, José Luis
author_browse Aparicio, Virginia Carolina
Costa, José Luis
De Geronimo, Eduardo
Dos Santos, Danilo Rheinheimer
Fernandes, Gracieli
Gonzalo Mayoral, Eliana Soledad
author_facet Gonzalo Mayoral, Eliana Soledad
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Fernandes, Gracieli
Dos Santos, Danilo Rheinheimer
Costa, José Luis
author_sort Gonzalo Mayoral, Eliana Soledad
collection INTA Digital
description Retention is one of the processes controlling the behavior and fate of pesticides in soil. The objective of this work was to evaluate the adsorption and desorption of glyphosate, AMPA, and metsulfuron-methyl in the main horizons of a Typic Argiudoll destined for agricultural use. For this purpose, the batch equilibrium method was used at a range of concentrations for each compound. Desorption was performed in three consecutive steps after the adsorption experiment. The results obtained showed strong adsorption of glyphosate and AMPA in the three horizons, following the trend B > A > C, with weak desorption. Metsulfuron-methyl, on the other hand, showed weak adsorption in the three horizons, following the trend A > B > C, with relevant desorption. Our results allow us to identify metsulfuron-methyl as the compound that poses the greatest environmental risk in terms of the potential contamination of other areas and groundwater. However, despite their strong adsorption and weak desorption, glyphosate and AMPA also represent potential contaminants of other environmental matrices.
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institution Instituto Nacional de Tecnología Agropecuaria (INTA -Argentina)
language Inglés
publishDate 2022
publishDateRange 2022
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spelling INTA121492022-06-23T17:18:52Z Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll Gonzalo Mayoral, Eliana Soledad Aparicio, Virginia Carolina De Geronimo, Eduardo Fernandes, Gracieli Dos Santos, Danilo Rheinheimer Costa, José Luis Adsorción Desorción Perfil del Suelo Plaguicidas Glifosato Adsorption Desorption Soil Profiles Pesticides Glyphosate Metsulfuron Retention is one of the processes controlling the behavior and fate of pesticides in soil. The objective of this work was to evaluate the adsorption and desorption of glyphosate, AMPA, and metsulfuron-methyl in the main horizons of a Typic Argiudoll destined for agricultural use. For this purpose, the batch equilibrium method was used at a range of concentrations for each compound. Desorption was performed in three consecutive steps after the adsorption experiment. The results obtained showed strong adsorption of glyphosate and AMPA in the three horizons, following the trend B > A > C, with weak desorption. Metsulfuron-methyl, on the other hand, showed weak adsorption in the three horizons, following the trend A > B > C, with relevant desorption. Our results allow us to identify metsulfuron-methyl as the compound that poses the greatest environmental risk in terms of the potential contamination of other areas and groundwater. However, despite their strong adsorption and weak desorption, glyphosate and AMPA also represent potential contaminants of other environmental matrices. EEA Balcarce Fil: Gonzalo Mayoral, Eliana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Fil: Gonzalo Mayoral, Eliana Soledad. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: Fernandes, Gracieli. Universidade Federal de Santa Maria. Centro de Ciências Rurais. Departamento de Solos; Brasil. Fil: Dos Santos, Danilo Rheinheimer. Universidade Federal de Santa Maria. Centro de Ciências Rurais. Departamento de Solos; Brasil. Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. 2022-06-23T17:08:21Z 2022-06-23T17:08:21Z 2022-05-03 info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://hdl.handle.net/20.500.12123/12149 https://www.tandfonline.com/doi/abs/10.1080/03601234.2022.2069982 0360-1234 (print) 1532-4109 (online) https://doi.org/10.1080/03601234.2022.2069982 eng info:eu-repograntAgreement/INTA/PNSUELO-1134044/AR./Destino ambiental y degradación de los pesticidas agregados al suelo. info:eu-repo/semantics/restrictedAccess application/pdf Taylor and Francis Journal of Environmental Science and Health, Part B (Published online: 03 May 2022)
spellingShingle Adsorción
Desorción
Perfil del Suelo
Plaguicidas
Glifosato
Adsorption
Desorption
Soil Profiles
Pesticides
Glyphosate
Metsulfuron
Gonzalo Mayoral, Eliana Soledad
Aparicio, Virginia Carolina
De Geronimo, Eduardo
Fernandes, Gracieli
Dos Santos, Danilo Rheinheimer
Costa, José Luis
Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title_full Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title_fullStr Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title_full_unstemmed Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title_short Glyphosate, AMPA, and metsulfuron-methyl retention in the main horizons of a typic argiudoll
title_sort glyphosate ampa and metsulfuron methyl retention in the main horizons of a typic argiudoll
topic Adsorción
Desorción
Perfil del Suelo
Plaguicidas
Glifosato
Adsorption
Desorption
Soil Profiles
Pesticides
Glyphosate
Metsulfuron
url http://hdl.handle.net/20.500.12123/12149
https://www.tandfonline.com/doi/abs/10.1080/03601234.2022.2069982
https://doi.org/10.1080/03601234.2022.2069982
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