Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine

Ethnopharmacological relevance: Fungal and bacterial infections remain a major problem worldwide, requiring the development of effective therapeutic strategies. Solanum mammosum L. (Solanaceae) (“teta de vaca”) is used in traditional medicine in Peru to treat fungal infections and respiratory disord...

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Autores principales: Cabanillas, Billy, Chassagne, François, Vásquez Ocmín, Pedro, Tahrioui, Ali, Chevalier, Sylvie, Vansteelandt, Marieke, Triastuti, Asih, Amasifuen Guerra, Carlos Alberto, Fabre, Nicolas, Haddad, Mohamed
Formato: Artículo
Lenguaje:Inglés
Publicado: El Sevier 2021
Materias:
Acceso en línea:https://hdl.handle.net/20.500.12955/1427
https://doi.org/10.1016/j.jep.2021.114473
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author Cabanillas, Billy
Chassagne, François
Vásquez Ocmín, Pedro
Tahrioui, Ali
Chevalier, Sylvie
Vansteelandt, Marieke
Triastuti, Asih
Amasifuen Guerra, Carlos Alberto
Fabre, Nicolas
Haddad, Mohamed
author_browse Amasifuen Guerra, Carlos Alberto
Cabanillas, Billy
Chassagne, François
Chevalier, Sylvie
Fabre, Nicolas
Haddad, Mohamed
Tahrioui, Ali
Triastuti, Asih
Vansteelandt, Marieke
Vásquez Ocmín, Pedro
author_facet Cabanillas, Billy
Chassagne, François
Vásquez Ocmín, Pedro
Tahrioui, Ali
Chevalier, Sylvie
Vansteelandt, Marieke
Triastuti, Asih
Amasifuen Guerra, Carlos Alberto
Fabre, Nicolas
Haddad, Mohamed
author_sort Cabanillas, Billy
collection Repositorio INIA
description Ethnopharmacological relevance: Fungal and bacterial infections remain a major problem worldwide, requiring the development of effective therapeutic strategies. Solanum mammosum L. (Solanaceae) (“teta de vaca”) is used in traditional medicine in Peru to treat fungal infections and respiratory disorders via topical application. However, the mechanism of action remains unknown, particularly in light of its chemical composition. Materials and methods: The antifungal activity of TDV was determined against Trichophyton mentagrophytes and Candida albicans using bioautography-TLC-HRMS to rapidly identify the active compounds. Then, the minimum inhibitory concentration (MIC) of the fruit crude extract and the active compound was determined to precisely evaluate the antifungal activity. Additionally, the effects of the most active compound on the formation of Pseudomonas aeruginosa biofilms and pyocyanin production were evaluated. Finally, a LC-HRMS profile and a molecular network of TDV extract were created to characterize the metabolites in the fruits' ethanolic extract. Results: Bioautography-TLC-HRMS followed by isolation and confirmation of the structure of the active compound by 1D and 2D NMR allowed the identification solamargine as the main compound responsible for the anti-Trichophyton mentagrophytes (MIC = 64 μg mL−1) and anti-Candida albicans (MIC = 64 μg mL−1) activities. In addition, solamargine led to a significant reduction of about 20% of the Pseudomonas aeruginosa biofilm formation. This effect was observed at a very low concentration (1.6 μg mL−1) and remained fairly consistent regardless of the concentration. In addition, solamargine reduced pyocyanin production by about 20% at concentrations of 12.5 and 50 μg mL−1. Furthermore, the LC-HRMS profiling of TDV allowed us to annotate seven known compounds that were analyzed through a molecular network. Conclusions: Solamargine has been shown to be the most active compound against T. mentoagrophytes and C. albicans in vitro. In addition, our data show that this compound affects significantly P. aeruginosa pyocyanin production and biofilm formation in our conditions. Altogether, these results might explain the traditional use of S. mammosum fruits to treat a variety of fungal infections and respiratory disorders.
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spelling INIA14272022-11-21T20:17:24Z Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine Cabanillas, Billy Chassagne, François Vásquez Ocmín, Pedro Tahrioui, Ali Chevalier, Sylvie Vansteelandt, Marieke Triastuti, Asih Amasifuen Guerra, Carlos Alberto Fabre, Nicolas Haddad, Mohamed Solanum mammosum Candida albicans Trichophyton mentagrophytes Pseudomonas acruginosa Bioautography Solamargine LC-HRMS https://purl.org/pe-repo/ocde/ford#4.04.02 Ethnopharmacological relevance: Fungal and bacterial infections remain a major problem worldwide, requiring the development of effective therapeutic strategies. Solanum mammosum L. (Solanaceae) (“teta de vaca”) is used in traditional medicine in Peru to treat fungal infections and respiratory disorders via topical application. However, the mechanism of action remains unknown, particularly in light of its chemical composition. Materials and methods: The antifungal activity of TDV was determined against Trichophyton mentagrophytes and Candida albicans using bioautography-TLC-HRMS to rapidly identify the active compounds. Then, the minimum inhibitory concentration (MIC) of the fruit crude extract and the active compound was determined to precisely evaluate the antifungal activity. Additionally, the effects of the most active compound on the formation of Pseudomonas aeruginosa biofilms and pyocyanin production were evaluated. Finally, a LC-HRMS profile and a molecular network of TDV extract were created to characterize the metabolites in the fruits' ethanolic extract. Results: Bioautography-TLC-HRMS followed by isolation and confirmation of the structure of the active compound by 1D and 2D NMR allowed the identification solamargine as the main compound responsible for the anti-Trichophyton mentagrophytes (MIC = 64 μg mL−1) and anti-Candida albicans (MIC = 64 μg mL−1) activities. In addition, solamargine led to a significant reduction of about 20% of the Pseudomonas aeruginosa biofilm formation. This effect was observed at a very low concentration (1.6 μg mL−1) and remained fairly consistent regardless of the concentration. In addition, solamargine reduced pyocyanin production by about 20% at concentrations of 12.5 and 50 μg mL−1. Furthermore, the LC-HRMS profiling of TDV allowed us to annotate seven known compounds that were analyzed through a molecular network. Conclusions: Solamargine has been shown to be the most active compound against T. mentoagrophytes and C. albicans in vitro. In addition, our data show that this compound affects significantly P. aeruginosa pyocyanin production and biofilm formation in our conditions. Altogether, these results might explain the traditional use of S. mammosum fruits to treat a variety of fungal infections and respiratory disorders. Abstract. 1. Introduction. 2. Material and methods. 3. Results. 4. Discussion. 5. Conclusion. References 2021-08-11T22:48:20Z 2021-08-11T22:48:20Z 2021-07-31 info:eu-repo/semantics/article Cabanillas, B.; Chassagne, F.; Vásquez, P.; Tahrioui, A.; Chevalier, S.; Vansteelandt, M.; Trastuti, A.; Amasifuen, C.; Fabre, N. & Haddad, M. (2021). Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine, Journal of Ethnopharmacology Volume 280, 114473. doi: 10.1016/j.jep.2021.114473. https://hdl.handle.net/20.500.12955/1427 Journal of Ethnopharmacology https://doi.org/10.1016/j.jep.2021.114473 eng Journal of Ethnopharmacology 280 (2021) 114473 https://doi.org/10.1016/j.jep.2021.114473 info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf application/pdf Perú El Sevier Reino Unido Instituto Nacional de Innovación Agraria Repositorio Institucional - INIA
spellingShingle Solanum mammosum
Candida albicans
Trichophyton mentagrophytes
Pseudomonas acruginosa
Bioautography
Solamargine
LC-HRMS
https://purl.org/pe-repo/ocde/ford#4.04.02
Cabanillas, Billy
Chassagne, François
Vásquez Ocmín, Pedro
Tahrioui, Ali
Chevalier, Sylvie
Vansteelandt, Marieke
Triastuti, Asih
Amasifuen Guerra, Carlos Alberto
Fabre, Nicolas
Haddad, Mohamed
Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title_full Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title_fullStr Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title_full_unstemmed Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title_short Pharmacological validation of Solanum mammosum L. as an anti-infective agent: Role of solamargine
title_sort pharmacological validation of solanum mammosum l as an anti infective agent role of solamargine
topic Solanum mammosum
Candida albicans
Trichophyton mentagrophytes
Pseudomonas acruginosa
Bioautography
Solamargine
LC-HRMS
https://purl.org/pe-repo/ocde/ford#4.04.02
url https://hdl.handle.net/20.500.12955/1427
https://doi.org/10.1016/j.jep.2021.114473
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