Surface and charge characteristics of selected soils in the tropics

Specific surface area and surface charge characteristics of some Alfisols and Ultisols from Nigeria were studied. Specific surface are measured by ethylene glycole retention was generally 2 to 3 times greater than the specific surface area measured by N2 adsorption for both surface and subsoil sampl...

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Main Authors: Gallez, A., Juo, A.S.R., Herbillon, A.
Format: Journal Article
Language:Inglés
Published: 1976
Subjects:
Online Access:https://hdl.handle.net/10568/80817
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author Gallez, A.
Juo, A.S.R.
Herbillon, A.
author_browse Gallez, A.
Herbillon, A.
Juo, A.S.R.
author_facet Gallez, A.
Juo, A.S.R.
Herbillon, A.
author_sort Gallez, A.
collection Repository of Agricultural Research Outputs (CGSpace)
description Specific surface area and surface charge characteristics of some Alfisols and Ultisols from Nigeria were studied. Specific surface are measured by ethylene glycole retention was generally 2 to 3 times greater than the specific surface area measured by N2 adsorption for both surface and subsoil samples. Soils derived from basalt had the greatest surface area per gram of clay as measured by both methods. The surface charge-pH curves of the soils bear the characteristic features of metallic oxides, indicating that surface charge behaviour of the soils studied follows the constant potential model. Values of PZC for Alfisol and Ultisol samples ranged from pH 3.0 to 3.9. Subsoils generally have higher PZC than corresponding surface horizons. Specific adsorption of sulfate resulted in a shift of the PZC to a higher value and an increase in the magnitude of positive charge. Cation and anion retention measurements showed that soils derived from basement complex rocks and sandstones contain negligible amount of positive charge while soils from basalts bear moderate amount of positive charge at their natural pH condition. Evidence also indicated that the Alfisols and Ultisols bear a small amount of permanent negative charge ranging from 1 to 4 meq/100 g.
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spelling CGSpace808172024-01-09T09:56:01Z Surface and charge characteristics of selected soils in the tropics Gallez, A. Juo, A.S.R. Herbillon, A. soil specitic surface area point of zero charge (pzc) allisols ultisols kaulinite Specific surface area and surface charge characteristics of some Alfisols and Ultisols from Nigeria were studied. Specific surface are measured by ethylene glycole retention was generally 2 to 3 times greater than the specific surface area measured by N2 adsorption for both surface and subsoil samples. Soils derived from basalt had the greatest surface area per gram of clay as measured by both methods. The surface charge-pH curves of the soils bear the characteristic features of metallic oxides, indicating that surface charge behaviour of the soils studied follows the constant potential model. Values of PZC for Alfisol and Ultisol samples ranged from pH 3.0 to 3.9. Subsoils generally have higher PZC than corresponding surface horizons. Specific adsorption of sulfate resulted in a shift of the PZC to a higher value and an increase in the magnitude of positive charge. Cation and anion retention measurements showed that soils derived from basement complex rocks and sandstones contain negligible amount of positive charge while soils from basalts bear moderate amount of positive charge at their natural pH condition. Evidence also indicated that the Alfisols and Ultisols bear a small amount of permanent negative charge ranging from 1 to 4 meq/100 g. 1976 2017-05-02T11:25:57Z 2017-05-02T11:25:57Z Journal Article https://hdl.handle.net/10568/80817 en Limited Access Gallez, A., Juo, A.S.R. & Herbillon, A. (1976). Surface and charge characteristics of selected soils in the tropics. Soil Science Society of America Journal, 40(4), 601-608.
spellingShingle soil
specitic surface area
point of zero charge (pzc)
allisols
ultisols
kaulinite
Gallez, A.
Juo, A.S.R.
Herbillon, A.
Surface and charge characteristics of selected soils in the tropics
title Surface and charge characteristics of selected soils in the tropics
title_full Surface and charge characteristics of selected soils in the tropics
title_fullStr Surface and charge characteristics of selected soils in the tropics
title_full_unstemmed Surface and charge characteristics of selected soils in the tropics
title_short Surface and charge characteristics of selected soils in the tropics
title_sort surface and charge characteristics of selected soils in the tropics
topic soil
specitic surface area
point of zero charge (pzc)
allisols
ultisols
kaulinite
url https://hdl.handle.net/10568/80817
work_keys_str_mv AT galleza surfaceandchargecharacteristicsofselectedsoilsinthetropics
AT juoasr surfaceandchargecharacteristicsofselectedsoilsinthetropics
AT herbillona surfaceandchargecharacteristicsofselectedsoilsinthetropics