13C-NMR assignments for methyls and muaternary carbons of the limonoid obacunone

The high field 1H and 13C resonances of obacunone were established by a series of 1D and 2D NMR experiments. The 13C-NMR signals of the five tertiary methyl groups and all quatenary carbons were unambiguously assigned. The results confirm the stereochemical assignments at alI stemgenic centres.

Detalles Bibliográficos
Autores principales: Rugutt, J.K., Fischer, N.H., Nauman, M.A., Schmidt, T.J., Berner, D.K.
Formato: Journal Article
Lenguaje:Inglés
Publicado: 1996
Materias:
Acceso en línea:https://hdl.handle.net/10568/180395
Descripción
Sumario:The high field 1H and 13C resonances of obacunone were established by a series of 1D and 2D NMR experiments. The 13C-NMR signals of the five tertiary methyl groups and all quatenary carbons were unambiguously assigned. The results confirm the stereochemical assignments at alI stemgenic centres.