Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review
Background: Renewable alternatives for bio-chemical production have gained significant attention. Glucose, as the most abundant monosaccharide globally, has emerged as a pivotal substrate in this pursuit. Consequently, the processes of glucose isomerization into fructose and glucose dehydration into...
| Main Authors: | , |
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| Format: | Journal Article |
| Language: | Inglés |
| Published: |
Elsevier
2024
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10568/148674 |
| _version_ | 1855521945303384064 |
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| author | Dharmapriya, Thakshila Nadeeshani Huang, P.-J. |
| author_browse | Dharmapriya, Thakshila Nadeeshani Huang, P.-J. |
| author_facet | Dharmapriya, Thakshila Nadeeshani Huang, P.-J. |
| author_sort | Dharmapriya, Thakshila Nadeeshani |
| collection | Repository of Agricultural Research Outputs (CGSpace) |
| description | Background: Renewable alternatives for bio-chemical production have gained significant attention. Glucose, as the most abundant monosaccharide globally, has emerged as a pivotal substrate in this pursuit. Consequently, the processes of glucose isomerization into fructose and glucose dehydration into 5-HMF have garnered substantial interest. 5-HMF (5-hydroxymethylfurfural) serves as a platform chemical, enabling the synthesis of valuable biobased compounds, while fructose stands out as a promising precursor for 5-HMF formation.
Method: Employing a comprehensive literature review methodology, this paper examines recent advancements in catalytic systems for the conversion of glucose on two primary processes: glucose isomerization into fructose and glucose dehydration into 5-HMF.
Significant Findings: This concise review centers on the use of amines as organic base catalysts for glucose isomerization, leading to high selectivity for fructose. It compares the yield and selectivity of fructose achieved with various homogeneous and heterogeneous amine catalysts. Furthermore, it highlights the growing interest in the MIL-101 series of Metal Organic Frameworks (MOFs) for direct glucose dehydration into 5-HMF, comparing the yield and selectivity of 5-HMF attained. This review serves as a guide for future researchers in biomass valorization, offering insights into recent advancements in catalysts for enhanced chemical production efficiency. |
| format | Journal Article |
| id | CGSpace148674 |
| institution | CGIAR Consortium |
| language | Inglés |
| publishDate | 2024 |
| publishDateRange | 2024 |
| publishDateSort | 2024 |
| publisher | Elsevier |
| publisherStr | Elsevier |
| record_format | dspace |
| spelling | CGSpace1486742025-10-26T12:52:09Z Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review Dharmapriya, Thakshila Nadeeshani Huang, P.-J. glucose dehydration conversion isomerization bio-based products catalytic activity chemical reactions fructose amines HMF biomass carbohydrates Background: Renewable alternatives for bio-chemical production have gained significant attention. Glucose, as the most abundant monosaccharide globally, has emerged as a pivotal substrate in this pursuit. Consequently, the processes of glucose isomerization into fructose and glucose dehydration into 5-HMF have garnered substantial interest. 5-HMF (5-hydroxymethylfurfural) serves as a platform chemical, enabling the synthesis of valuable biobased compounds, while fructose stands out as a promising precursor for 5-HMF formation. Method: Employing a comprehensive literature review methodology, this paper examines recent advancements in catalytic systems for the conversion of glucose on two primary processes: glucose isomerization into fructose and glucose dehydration into 5-HMF. Significant Findings: This concise review centers on the use of amines as organic base catalysts for glucose isomerization, leading to high selectivity for fructose. It compares the yield and selectivity of fructose achieved with various homogeneous and heterogeneous amine catalysts. Furthermore, it highlights the growing interest in the MIL-101 series of Metal Organic Frameworks (MOFs) for direct glucose dehydration into 5-HMF, comparing the yield and selectivity of 5-HMF attained. This review serves as a guide for future researchers in biomass valorization, offering insights into recent advancements in catalysts for enhanced chemical production efficiency. 2024-09 2024-06-24T10:37:52Z 2024-06-24T10:37:52Z Journal Article https://hdl.handle.net/10568/148674 en Open Access Elsevier Dharmapriya, Thakshila Nadeeshani; Huang, P.-J. 2024. Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review. Journal of the Taiwan Institute of Chemical Engineers, 162:105585. [doi: https://doi.org/10.1016/j.jtice.2024.105585] |
| spellingShingle | glucose dehydration conversion isomerization bio-based products catalytic activity chemical reactions fructose amines HMF biomass carbohydrates Dharmapriya, Thakshila Nadeeshani Huang, P.-J. Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title | Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title_full | Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title_fullStr | Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title_full_unstemmed | Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title_short | Exploring recent significant catalytic systems for the conversion of glucose into bio-based chemicals: a concise review |
| title_sort | exploring recent significant catalytic systems for the conversion of glucose into bio based chemicals a concise review |
| topic | glucose dehydration conversion isomerization bio-based products catalytic activity chemical reactions fructose amines HMF biomass carbohydrates |
| url | https://hdl.handle.net/10568/148674 |
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